Chapter 7 Learning Objectives:
- Be able to define:
- Describe the structure of alkenes, including hybridization, bonds, and
bond angles.
- Identify elements of unsaturation.
- Determine the degree of unsaturation for a molecule given the structure or
molecular formula.
- Draw molecules of a given molecular formula with the appropriate degree of
unsaturation.
- Correctly name a given alkene, cycloalkene, diene, etc. using the IUPAC
system of nomenclature.
- Provide the common names for alkenes and alkenyl substituents discussed in
class.
- Draw the structure of an alkene, cycloalkene, diene, etc. given the IUPAC
name.
- Determine the number of geometric isomers for a given alkene, diene,
triene, etc.
- Classify a given alkene as cis, trans, E,
or Z.
- Determine the relative stabilities of a series of alkenes using heats of
hydrogenation or molecular structure.
- Predict trends in physical properties for a series of alkenes.
- Draw the Zaitsev and Hofmann products for a given reaction.
- Describe the conditions under which the Zaitsev or Hofmann product will be
favored.
- Identify atoms which are anti-coplanar or trans-diaxial
to one another.
- Describe the preparation of alkenes from alkyl halides (dehydrohalogenation),
including regiochemistry and stereochemistry. Predict the major product of a
dehydrohalogenation reaction. Draw the mechanism(s) for a
dehydrohalogenation reaction.
- Describe the preparation of alkenes from alcohols (dehydration), including
regiochemistry and stereochemistry. Predict the major product of a
dehydration reaction. Draw the mechanism for a dehydration reaction.